Gold Mineralization of the Gatsuurt Deposit in the North Khentei Gold Belt,Central Northern Mongolia     

Chinbat Khishgee  Masahide Akasaka  Hiroto Ohira  Jargalan Sereenen 《Resource Geology》2014,64(1):1-16

Mineral assemblages, chemical compositions of ore minerals, wall rock alteration and fluid inclusions of the Gatsuurt gold deposit in the North Khentei gold belt of Mongolia were investigated to characterize the gold mineralization, and to clarify the genetic processes of the ore minerals. The gold mineralization of the deposit occurs in separate Central and Main zones, and is characterized by three ore types: (i) low‐grade disseminated and stockwork ores; (ii) moderate‐grade quartz vein ores; and (iii) high‐grade silicified ores, with average Au contents of approximately 1, 3 and 5 g t^?1 Au, respectively. The Au‐rich quartz vein and silicified ore mineralization is surrounded by, or is included within, the disseminated and stockwork Au‐mineralization region. The main ore minerals are pyrite (pyrite‐I and pyrite‐II) and arsenopyrite (arsenopyrite‐I and arsenopyrite‐II). Moderate amounts of galena, tetrahedrite‐tennantite, sphalerite and chalcopyrite, and minor jamesonite, bournonite, boulangerite, geocronite, scheelite, geerite, native gold and zircon are associated. Abundances and grain sizes of the ore minerals are variable in ores with different host rocks. Small grains of native gold occur as fillings or at grain boundaries of pyrite, arsenopyrite, sphalerite, galena and tetrahedrite in the disseminated and stockwork ores and silicified ores, whereas visible native gold of variable size occurs in the quartz vein ores. The ore mineralization is associated with sericitic and siliceous alteration. The disseminated and stockwork mineralization is composed of four distinct stages characterized by crystallization of (i) pyrite‐I + arsenopyrite‐I, (ii) pyrite‐II + arsenopyrite‐II, (iii) galena + tetrahedrite + sphalerite + chalcopyrite + jamesonite + bournonite + scheelite, and iv) boulangerite + native gold, respectively. In the quartz vein ores, four crystallization stages are also recognized: (i) pyrite‐I, (ii) pyrite‐II + arsenopyrite + galena + Ag‐rich tetrahedrite‐tennantite + sphalerite + chalcopyrite + bournonite, (iii) geocronite + geerite + native gold, and (iv) native gold. Two mineralization stages in the silicified ores are characterized by (i) pyrite + arsenopyrite + tetrahedrite + chalcopyrite, and (ii) galena + sphalerite + native gold. Quartz in the disseminated and stockwork ores of the Main zone contains CO₂‐rich, halite‐bearing aqueous fluid inclusions with homogenization temperatures ranging from 194 to 327°C, whereas quartz in the disseminated and stockwork ores of the Central zone contains CO₂‐rich and aqueous fluid inclusions with homogenization temperatures ranging from 254 to 355°C. The textures of the ores, the mineral assemblages present, the mineralization sequences and the fluid inclusion data are consistent with orogenic classification for the Gatsuurt deposit.  相似文献   

The Crater Mountain Deposit,Papua New Guinea: Porphyry‐related Au–Te System     

Shadrach K. Noku  Masahide Akasaka  Hiroharu Matsueda 《Resource Geology》2011,61(1):63-75

Ore mineralization and wall rock alteration of Crater Mountain gold deposit, Papua New Guinea, were investigated using ore and host rock samples from drill holes for ore and alteration mineralogical study. The host rocks of the deposit are quartz‐feldspar porphyry, feldspar‐hornblende porphyry, andesitic volcanics and pyroclastics, and basaltic‐andesitic tuff. The main ore minerals are pyrite, sphalerite, galena, chalcopyrite and moderate amounts of tetrahedrite, tennantite, pyrrhotite, bornite and enargite. Small amounts of enargite, tetradymite, altaite, heyrovskyite, bismuthinite, bornite, idaite, cubanite, native gold, CuPbS₂, an unidentified Bi‐Te‐S mineral and argentopyrite occur as inclusions mainly in pyrite veins and grains. Native gold occurs significantly in the As‐rich pyrite veins in volcanic units, and coexists with Bi‐Te‐S mineral species and rarely with chalcopyrite and cubanite relics. Four mineralization stages were recognized based on the observations of ore textures. Stage I is characterized by quartz‐sericite‐calcite alteration with trace pyrite and chalcopyrite in the monomict diatreme breccias; Stage II is defined by the crystallization of pyrite and by weak quartz‐chlorite‐sericite‐calcite alteration; Stage III is a major ore formation episode where sulfides deposited as disseminated grains and veins that host native gold, and is divided into three sub‐stages; Stage IV is characterized by predominant carbonitization. Gold mineralization occurred in the sub‐stages 2 and 3 in Stage III. The fS₂ is considered to have decreased from ～10^?2 to 10^?14 atm with decreasing temperature of fluid.  相似文献   

Distribution of cations at two tetrahedral sites in Ca2MgSi2O7-Ca2Fe3+AlSiO7 series synthetic melilite and its relation to incommensurate structure     

Maki Hamada  Masahide Akasaka 《Physics and Chemistry of Minerals》2013,40(3):259-270

Synthetic melilites on the join Ca₂MgSi₂O₇ (åkermanite: Ak)-Ca₂Fe³⁺AlSiO₇ (ferrialuminium gehlenite: FAGeh) were studied using X-ray powder diffraction and ⁵⁷Fe Mössbauer spectroscopic methods to determine the distribution of Fe³⁺ between two different tetrahedral sites (T1 and T2), and the relationship between ionic substitution and incommensurate (IC) structure. Melilites were synthesized from starting materials with compositions of Ak₁₀₀, Ak₈₀FAGeh₂₀, Ak₇₀FAGeh₃₀ and Ak₅₀FAGeh₅₀ by sintering at 1,170–1,350 °C and 1 atm. The average chemical compositions and end-member components, Ak, FAGeh and Geh (Ca₂Al₂SiO₇), of the synthetic melilites were Ca_2.015Mg_1.023Si_1.981O₇ (Ak₁₀₀), Ca_2.017Mg_0.788Fe _0.187 ³⁺ Al_0.221Si_1.791O₇ (Ak₇₈FAGeh₁₉Geh₃), Ca_1.995Mg_0.695Fe _0.258 ³⁺ Al_0.318Si_1.723O₇ (Ak₆₉FAGeh₂₅Geh₆) and Ca_1.982Mg_0.495Fe _0.449 ³⁺ Al_0.519Si_1.535O₇ (Ak₄₉FAGeh₄₄Geh₇), respectively. Rietveld refinements using X-ray powder diffraction data measured using CuK _α -radiation at room temperature converged successfully with goodness-of-fits of 1.15–1.26. The refined Fe occupancies at the T1 and T2 sites and the Mg and Si contents determined by electron microprobe analysis gave the site populations of [0.788Mg + 0.082Fe³⁺ + 0.130Al]_T1[0.104Fe³⁺ + 0.104Al + 1.792Si]_T2 for Ak₇₈FAGeh₁₉Geh₃, [0.695Mg + 0.127Fe³⁺ + 0.178Al]_T1[0.132Fe³⁺ + 0.144Al + 1.724Si]_T2 for Ak₆₉FAGeh₂₅Geh₆ and [0.495Mg + 0.202Fe³⁺ + 0.303Al]_T1[0.248Fe³⁺ + 0.216Al + 1.536Si]_T2 for Ak₄₉FAGeh₄₄Geh₇ (apfu: atoms per formula unit), respectively. The results indicate that Fe³⁺ is distributed at both the T1 and the T2 sites. The mean T1–O distance decreases with the substitution of Fe³⁺ + Al³⁺ for Mg²⁺ at the T1 site, whereas the mean T2–O distance increases with substitution of Fe³⁺ + Al³⁺ for Si⁴⁺ at the T2 site, causing decrease in the a dimension and increase in the c dimension. However, in spite of the successful Rietveld refinements for the X-ray powder diffraction data measured using CuK _α-radiation at room temperature, each Bragg reflection measured using CuK _α1-radiation at room temperature showed weak shoulders, which were not observed in those measured at 200 °C. The Mössbauer spectra of the melilites measured at room temperature consist of two doublets assigned to Fe³⁺ at the T1 site and two or three doublets to Fe³⁺ at the T2 site, implying the existence of multiple T1 and T2 sites with different site distortions. These facts can be interpreted in terms of the IC structure in all synthetic melilites at room temperature, respectively. The results of Mössbauer analysis indicate that the IC structure in melilite is caused by not only known multiple T1 site, but also multiple T2 site at room temperature.  相似文献   

A computational model for dynamic strain localization in unsaturated elasto-viscoplastic soils     

Fusao Oka  Babak Shahbodagh  Sayuri Kimoto 《国际地质力学数值与分析法杂志》2019,43(1):138-165

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Basin-scale distribution of NH<Subscript>4</Subscript><Superscript>+</Superscript> and NO<Subscript>2</Subscript><Superscript>−</Superscript> in the Pacific Ocean     

Sayaka Yasunaka  Yukihiro Nojiri  Taketo Hashioka  Chisato Yoshikawa  Taketoshi Kodama  Shin-ichiro Nakaoka  Sanae Chiba  Fuminori Hashihama  Masahide Wakita  Ken Furuya  Daisuke Sasano  Akihiko Murata  Hiroshi Uchida  Michio Aoyama 《Journal of Oceanography》2018,74(1):1-11

We used more than 25,000 nutrient samples to elucidate for the first time basin-scale distributions and seasonal changes of surface ammonium (NH₄ ⁺) and nitrite (NO₂ ^?) concentrations in the Pacific Ocean. The highest NH₄ ⁺, NO₂ ^?, and nitrate (NO₃ ^?) concentrations were observed north of 40°N, in the coastal upwelling region off the coast of Mexico, and in the Tasman Sea. NH₄ ⁺ concentrations were elevated during May–October in the western subarctic North Pacific, May–December in the eastern subarctic North Pacific, and June–September in the subtropical South Pacific. NO₂ ^? concentrations were highest in winter in both hemispheres. The seasonal cycle of NH₄ ⁺ was synchronous with NO₂ ^?, NO₃ ^?, and satellite chlorophyll a concentrations in the western subtropical South Pacific, whereas it was synchronous with chlorophyll-a but out of phase with NO₂ ^? and NO₃ ^? in the subarctic regions.  相似文献   

Limits on isocurvature perturbations from non-Gaussianity in WMAP temperature anisotropy     

Chiaki Hikage  Kazuya Koyama  Takahiko Matsubara  Tomo Takahashi  Masahide Yamaguchi 《Monthly notices of the Royal Astronomical Society》2009,398(4):2188-2198

We study the effect of primordial isocurvature perturbations on non-Gaussian properties of cosmic microwave background (CMB) temperature anisotropies. We consider generic forms of the non-linearity of isocurvature perturbations which can be applied to a wide range of theoretical models. We derive analytical expressions for the bispectrum and the Minkowski Functionals for CMB temperature fluctuations to describe the non-Gaussianity from isocurvature perturbations. We find that the isocurvature non-Gaussianity in the quadratic isocurvature model, where the isocurvature perturbation S is written as a quadratic function of the Gaussian variable  σ,  S =σ²−〈σ²〉  , can give the same signal-to-noise ratio as   f _NL= 30  even if we impose the current observational limit on the fraction of isocurvature perturbations contained in the primordial power spectrum α. We give constraints on isocurvature non-Gaussianity from Minkowski Functionals using the Wilkinson Microwave Anisotropy Probe ( WMAP ) 5-year data. We do not find a significant signal of isocurvature non-Gaussianity. For the quadratic isocurvature model, we obtain a stringent upper limit on the isocurvature fraction  α < 0.070  (95 per cent CL) for a scale-invariant spectrum which is comparable to the limit obtained from the power spectrum.  相似文献   

Methodology of analysis associating survey results by the filter-pack method with those of precipitation- Acid-base balance on acid-related and alkali-related chemical species in urban ambient air and its influence on the acidification of precipitation -     

Masahide Aikawa  Takatoshi Hiraki 《Journal of Atmospheric Chemistry》2008,61(1):21-29

Continuous weekly monitoring on the concentration of gases and aerosols in urban ambient air by a four-stage filter-pack method was carried out for 7 years in order to study not only the acid-base balance of acid-related (HNO₃, NO₃ ⁻, and non-sea-salt-(nss-)SO₄ ²⁻) and alkali-related (NH₃, NH₄ ⁺, and nss-Ca²⁺) chemical species but also its influence on the acidification of precipitation. The concentrations of the total nitrate (= NO₃⁻ + HNO₃) and nss-SO₄²⁻ showed a similar seasonal variation: high in the summer and low in the winter. The total nitrate and nss-SO₄²⁻ accounted for 0.43 and 0.57 of the acid-related species, respectively, on an equivalent basis. The total ammonium (= NH₃ + NH₄⁺) accounted for more than 0.9 of the alkali-related species, except for a springtime nss-Ca²⁺ episodic peak. The alkali-related species were generally overabundant compared with the acid-related species in the HNO₃-NO₃⁻-nss-SO₄²⁻-NH₃-NH₄⁺-nss-Ca²⁺ system. The alkali-rich distribution was especially pronounced in the winter, but the acid-related species was comparable to the alkali-related species in the summer, which was attributed to the larger H⁺ deposition by precipitation in the summer. This study can provide a methodology to associate survey results obtained by a filter-pack method with those of precipitation.  相似文献   

Simulated interannual variation in summertime atmospheric circulation associated with the East Asian monsoon     

Miki Arai  Masahide Kimoto 《Climate Dynamics》2008,31(4):435-447

The reproducibility of the interannual variability of the summertime East Asian circulation is examined using an atmospheric general circulation model (AGCM). An ensemble experiment is conducted using observed sea surface temperature (SST) of recent 20 years as a lower boundary condition. The spatial pattern associated with the first principal mode of observation of geopotential height at 500 hPa is characterized by a meridional wavy pattern extending over eastern Siberia, the vicinity of Japan and the subtropical western Pacific. The principal component (PC) time series of the leading mode is represented well by a high-resolution version of the AGCM with horizontal resolution T106 and with 56 vertical levels (T106L56), while with a lower resolution version, T42 and 20 vertical levels, the reproducibility is considerably degraded. The reproducibility by the AGCM suggests the importance of SST as a boundary condition. However, the simulated interannual variations show the alternating appearance of two distinct circulation regimes, a cold summer regime and a hot summer regime, exhibiting interesting bimodality in probability density distribution in PC phase space. This implies that the system’s response to the continuously varying boundary condition includes nonlinearity. The nature of this nonlinearity is suggested to be wave breaking in the westerly region of the high latitudes that requires high resolution for the reproduction. Using the T106L56 model, another ensemble experiment was carried out with doubled CO₂. The climate change appears as an increase in residence frequency of the cold summer regime of the principal patterns of the present-day climate. This paper is a contribution to the AMIP-CMIP Diagnostic Sub-project on General Circulation Model Simulation of the East Asian Climate, coordinated by W.-C. Wang.  相似文献   

Fast and slow timescales in the tropical low-cloud response to increasing CO2 in two climate models     

Masahiro Watanabe  Hideo Shiogama  Masakazu Yoshimori  Tomoo Ogura  Tokuta Yokohata  Hajime Okamoto  Seita Emori  Masahide Kimoto 《Climate Dynamics》2012,39(7-8):1627-1641

To obtain physical insights into the response and feedback of low clouds (C _l ) to global warming, ensemble 4?×?CO₂ experiments were carried out with two climate models, the Model for Interdisciplinary Research on Climate (MIROC) versions 3.2 and 5. For quadrupling CO₂, tropical-mean C _l decreases, and hence, acts as positive feedback in MIROC3, whereas it increases and serves as negative feedback in MIROC5. Three time scales of tropical-mean C _l change were identified—an initial adjustment without change in the global-mean surface air temperature, a slow response emerging after 10–20?years, and a fast response in between. The two models share common features for the former two changes in which C _l decreases. The slow response reflects the variability of C _l associated with the El Ni?o-Southern Oscillation in the control integration, and may therefore be constrained by observations. However, the fast response is opposite in the two models and dominates the total response of C _l . Its sign is determined by a subtle residual of the C _l increase and decrease over the ascending and subsidence regions, respectively. The regional C _l increase is consistent with a more frequent occurrence of a stable condition, and vice versa, as measured by lower-tropospheric stability (LTS). The above frequency change in LTS is similarly found in six other climate models despite a large difference in both the mean and the changes in the low-cloud fraction for a given LTS. This suggests that the response of the thermodynamic constraint for C _l to increasing CO₂ concentrations is a robust part of the climate change.  相似文献   

Silver-Bearing and Associated Minerals in El Zancudo Deposit, Antioquia, Colombia     

Alba Nury Gallego Hernández  Masahide Akasaka 《Resource Geology》2007,57(4):386-399

The occurrence and the chemical compositions of ore minerals (especially the silver‐bearing minerals) and fluid inclusions of the El Zancudo mine in Colombia were investigated in order to analyze the genetic processes of the ore minerals and to examine the genesis of the deposit. The El Zancudo mine is a silver–gold deposit located in the western flank of the Central Cordillera in Antioquia Department. It consists mainly of banded ore veins hosted in greenschist and lesser disseminated ore in porphyritic rocks. The ore deposit is associated with extensive hydrothermally altered zones. The ores from the banded veins contain sphalerite, pyrite, arsenopyrite, galena, Ag‐bearing sulfosalts, Pb‐Sb sulfosalts, and minor chalcopyrite, electrum, and native silver. Electrum is included within sphalerite, pyrite, and arsenopyrite, and is also partially surrounded by pyrite, arsenopyrite, sphalerite, and tetrahedrite. Native silver is present in minor amounts as small grains in contact with Ag‐rich sulfosalts. Silver‐bearing sulfosalts are argentian tetrahedrite–freibergite solid solution, andorite, miargyrite, diaphorite, and owyheeite. Pb‐Sb sulfosalts are bournonite, jamesonite, and boulangerite. Two main crystallization stages are recognized, based on textural relations and mineral assemblages. The first‐stage assemblage includes sphalerite, pyrite, arsenopyrite, galena and electrum. The second stage is divided into two sub‐stages. The first sub‐stage commenced with the deposition and growth of sphalerite, pyrite, and arsenopyrite. These minerals are characterized by compositional growth banding, and seem to have crystallized continuously until the end of the second sub‐stage. Tetrahedrite, Pb‐Cu sulfosalts, Ag‐Sb sulfosalt, and Pb‐Ag‐Sb sulfosalts crystallized from the final part of the first sub‐stage and during the whole second sub‐stage. However, one Pb‐Ag‐Sb sulfosalt, diaphorite, was formed by a retrograde reaction between galena and miargyrite. The minimum and maximum genetic temperatures estimated from the FeS content of sphalerite coexisting with pyrite and the silver content of electrum are 300°C and 420°C, respectively. These estimated genetic temperatures are similar to, but slightly higher than the homogenization temperatures (235–350°C) of primary fluid inclusions in quartz. The presence of muscovite in the altered host rocks and gangue suggest that the pH of the hydrothermal solutions was close to neutral. Most of the sulfosalts in this deposit have previously been attributed as the products of epithermal mineralization. However, El Zancudo can be classified as a xenothermal deposit, in view of the low pressure and high temperature genetic conditions identified in the present study, based on the mineralogy of sulfosalts and the homogenization temperatures of the fluid inclusions.  相似文献